Search results for "Site selective"

Triazole vs. triazolium carbene ligands in the site-selective cyclometallation of o-carboranes by M(iii) (M = Ir, Rh) complexes

2018

Ir(iii) and Rh(iii)-mediated site-selective cage B-H and C-H bond activation in o-carboranylmethyl derivatives has been achieved. The selectivity of the reaction is related to the electron donating properties of the ligand. 1,2,3-Triazole-derivatives use the N2 position of the triazole ring to direct the selective o-carborane B-H bond activation, whereas the corresponding triazolylidene derivatives lead to the cage C-H bond activation with complete site-selectivity.

ChemInform Abstract: Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of α-Halomethyl Oxime Ethers and Site-Selective Cross-Coupling of Dihalo Deriv…

2014

The Pd-catalyzed cross-coupling reaction of chloromethyl oxime ethers with a wide range of aryl-, heteroaryl-, and vinylboronic acids proceeds with good yields.

Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of α-Halomethyl Oxime Ethers and Site-Selective Cross-Coupling of Dihalo Derivatives

2013

The Pd-catalyzed cross-coupling reaction of chloromethyl oxime ethers with a wide range of aryl-, heteroaryl-, and vinylboronic acids proceeds with good yields.

Corrigendum to “Light-induced, site-selective isomerization of glyoxylic acid in solid xenon” [Chem. Phys. Lett. 616–617 (2014) 91–97]

2015